
In this time of relative isolation from friends and professional colleagues, CorroZoom seeks to build and maintain a worldwide community of scientists with mutual interests in the area of corrosion science. This webinar series will be free to everyone in the world. CorroZoom is not associated with any professional organization or society. An informal organizing committee has selected the speakers. Should it prove successful and the need continue, more speakers will be added.
Each webinar will only be synchronous, live only – you must be logged on to see it. The webinars will include a presentation of about 45 min in length and a discussion of about 15 min. Every participant will be able to submit questions for the speaker in the Zoom Q&A box, which will be handled by a moderator.
On 1 December 2022, the CorroZoom webinar will start at these times worldwide:
0800 | Columbus (US Eastern) |
1000 | Sao Paulo |
1300 | London |
1400 | Paris |
1600 | Istanbul |
1630 | Tehran |
1830 | Mumbai |
2100 | Beijing |
2200 | Tokyo |
0000 | Melbourne (next day) |
Second CorroZoom Season 3 Webinar- V.S. Raja
First CorroZoom Season 3 Webinar- Robert G. Kelly
Sixth CorroZoom Season 2 Webinar- Ingrid Milošev
Fifth CorroZoom Season 2 Webinar - Hiroki Habazaki
Fourth CorroZoom Season 2 Webinar - Jenifer Locke
Third CorroZoom Season 2 Webinar - Karl Sieradzki
Second CorroZoom Season 2 Webinar - Arjan Mol
First CorroZoom Season 2 Webinar - Xiaogang Li
Sixth CorroZoom Webinar – Anton Kokalj
Fifth CorroZoom Webinar – Sanna Virtanen
Fourth CorroZoom Webinar – Gerald S. Frankel
Third CorroZoom Webinar - John R. Scully
Third CorroZoom Season 3 Webinar - Roger Newman
2 March 2023 at 0800 US Eastern
To register (free for all):
https://osu.zoom.us/webinar/register/WN_uVkt8yKkQX-k_jodqB8zPA
The effect of alloy composition on molten salt corrosion- Dealloying, but not as we know it
Roger Newman
University of Toronto, Canada
Abstract
This talk will be based mainly on the recent PhD research of Dr. Touraj Ghaznavi, with other comparison material as required. Molten salt corrosion is topical in several technologies, including small modular molten-salt nuclear reactors. Our research has been focused on NiFe and NiCrFe alloys, but the general principles should be applicable to other solid-solution alloy systems that show dealloying, with the formation of nano- or micro-porous dealloyed layers.
There are two kinds of dealloying threshold, or parting limit, that are familiar at ambient temperatures in aqueous electrolytes. One is in the 50-60 at.% range of less-noble (LN) metal content (example: AuAg). The other is close to 20 at.% LN content (example: CuZn). Both these compositions have a meaning within percolation theory, as discussed by Artymowicz et al. [1]. It is recognized that increasing kinetics of surface diffusion of the more-noble (MN) metal (or surface exchange of MN metal and its ions, as in the brass example) reduce the parting limit by exposing otherwise inaccessible paths rich in LN metal. With this background, we can expect a further reduction in the parting limit at the high temperatures where we get molten salt corrosion. We can also expect that with sufficient increase in temperature, lattice diffusion of alloying elements will start to affect the kinetics and/or the morphology of the dealloyed material. Both these expectations have been realized in Dr. Ghaznavi’s work using molten chloride salts, but with several surprises along the way.
[1] D.M. Artymowicz, J. Erlebacher, and R.C. Newman, Relationship between the parting limit for de-alloying and a particular geometric high-density site percolation threshold, Philosophical Magazine 89(21) (2009) 1663-1693.
Biography
Roger Newman is Professor and UNENE Research Chair in the Department of Chemical Engineering and Applied Chemistry at the University of Toronto (UofT). Before joining UofT in 2004, he spent 20 years in the Corrosion and Protection Centre, UMIST, Manchester, UK. Prior to that, he spent several years at Brookhaven National Laboratory in the US. His main research interests have been localized corrosion, stress corrosion cracking, passivity, and dealloying. He also has an active program in metallic nanomaterials. He has ongoing research with the nuclear power, nuclear waste management, and natural gas (GTL) industries. Some decades ago, he was very active in corrosion issues in the pulp and paper industry, and oil and gas production.
CorroZoom Updates
Season 2 of CorroZoom has ended as of the last webinar on 31 May 2022. You can view the list of speakers from season 1 and season 2 in the tab marked “Previous Webinars.” You will also find links to recordings of some of the previous webinars.
The list of speakers of CorroZoom Season 3 will be announced here when it is available and by email to people for whom we have email addresses. If you are not on the CorroZoom email distribution list but want to be added, please send an email to guo.237@osu.edu.
Thanks to everyone for making season 1 and season 2 of CorroZoom a huge success!